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Cationic Polymerization Behavior of 1,3,2-Dioxathiepane 2-Oxide: First Cationic Ring-Opening Polymerization of Cyclic Sulfite

โœ Scribed by Azuma, Natsuhiro; Takata, Toshikazu; Sanda, Fumio; Endo, Takeshi

Book ID
126278249
Publisher
American Chemical Society
Year
1995
Tongue
English
Weight
324 KB
Volume
28
Category
Article
ISSN
0024-9297

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Cationic polymerization behavior of seven-membered cyclic sulfite
โœ Natsuhiro Azuma; Fumio Sanda; Toshikazu Takata; Takeshi Endo ๐Ÿ“‚ Article ๐Ÿ“… 1997 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 237 KB ๐Ÿ‘ 2 views

Cationic ring-opening polymerization behavior of a seven-membered cyclic sulfite ( 1) was examined. 1 was prepared by the reaction of 1,4-butanediol with SOCl 2 in 58% yield. The cationic polymerization of 1 was carried out at 0, 25, 60, or 100ะŠC with trifluoromethanesulfonic acid (TfOH), methyl tri