By use of carbon black containing quaternary ammonium carboxylate (COO-N+Rd groups as catalyst, the anionic ring opening polymerization of P-propiolactone (PL) was carried out a t 5OOC. Although carbon black itself was unable to initiate the polymerization of PL, carbon black containing COO-N+R,j gr
โฆ LIBER โฆ
Cationic grafting from carbon black. III. Grafting of polyesters from carbon black by ring-opening polymerization of lactones initiated by CO+ClO groups on carbon black
โ Scribed by Norio Tsubokawa
- Publisher
- John Wiley and Sons
- Year
- 1985
- Tongue
- English
- Weight
- 433 KB
- Volume
- 30
- Category
- Article
- ISSN
- 0021-8995
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The introduction of peroxide groups onto carbon black surface was achieved through the trapping of the peroxide radicals formed by the decomposition of polymeric peroxide, such as poly(tetraethy1ene glycol peroxyadipate) (ATPPO), and bis-peroxide, such as l,l'-bis(t-buty1dioxy)cyclohexane (Perhexa-C