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Cationic Gold(I) Complexes of 2,4,6-Tri- tert -butyl-1,3,5-triphosphabenzene

✍ Scribed by Townsend, Nell S.; Green, Michael; Russell, Christopher A.

Book ID: 126307175
Publisher: American Chemical Society
Year: 2012
Tongue: English
Weight: 823 KB
Volume: 31
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om201265n

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## Abstract Treatment of the lithium amide Li[NPh(SiMe~3~)] with 2,4,6‐tri‐__tert__‐butyl‐1,3,5‐triphosphabenzene, P~3~C~3~__t__Bu~3~, in a 1:2 ratio afforded equimolar amounts of the lithium salt of the five‐membered 2,4,5‐tri‐__tert__‐butyl‐1,3‐diphospholide anion, LiP~2~C~3~__t__Bu~3~ (isolated