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Cationic di- and mono-carbonyl complexes of manganese(I)

✍ Scribed by G.A. Carriedo; J. Gimeno; M. Laguna; V. Riera

Publisher
Elsevier Science
Year
1981
Tongue
English
Weight
636 KB
Volume
219
Category
Article
ISSN
0022-328X

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## Abstract Some new low‐valent, cationic complexes of technetium‐99 have been prepared. Oxidation of Tc~2~(CO)~10~ (1) with NOPF~6~ in acetonitrile gave [Tc(CH~3~CN)(CO)~5~]PF~6~ (2) quantitatively. This complex constitutes a useful precursor for cationic carbonyl complexes, as exemplified by a va