Cationic copolymerization of β-propiolactone and 1,3-dioxolane
✍ Scribed by L.K. Pakhomova; A.A. Berlin; I.S. Morozova; A.T. Ponomarenko
- Book ID
- 118965885
- Publisher
- Elsevier Science
- Year
- 1978
- Weight
- 688 KB
- Volume
- 20
- Category
- Article
- ISSN
- 0032-3950
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Photoinitiated polymerization of 4-methylene-2-phenyl-1,3-dioxolane ( 1) was carried out using either tris(4-methylphenyl)sulfonium hexafluoroantimonate or 4-decyloxyphenyl phenyliodonium hexafluoroantimonate as initiators. 1 H-NMR analyses confirmed exclusive ring-opening while DSC and SEC were use
Copolymers of the cyclic ketene acetals, 2-methylene-5,5-dimethyl-1,3-dioxane, 3, (MJ with 2-methylene-l,3-dioxolane, 4, (M2) or 2-methylene-1,3-dioxane, 5, (M2), were synthesized by cationic copolymerization. An experimental method was designed to study the reactivity of these very reactive and ext