𝔖 Bobbio Scriptorium

✦ LIBER ✦

Cationic alkylidyne trirhodium cluster complexes. Crystal structure [(.eta.5-C5H5)3Rh3(.mu.-CO)2(.mu.3-CH)]PF6[tris(.eta.5-cyclopentadienyl)-bis(.mu.2-carbonyl)-.mu.3-methylidyne-trirhodium] hexafluorophosphate

✍ Scribed by Dimas, P. A.; Duesler, E. N.; Lawson, R. J.; Shapley, J. R.

Book ID: 126154205
Publisher: American Chemical Society
Year: 1980
Tongue: English
Weight: 411 KB
Volume: 102
Category: Article
ISSN: 0002-7863
DOI: 10.1021/ja00546a030

No coin nor oath required. For personal study only.

📜 SIMILAR VOLUMES

Reaction of cyclopentadiene with (alkyli

Reaction of cyclopentadiene with (alkylidyne)triruthenium clusters. Syntheses of Ru3(.mu.3-CPh)(.mu.-CO)2(CO)6(.eta.5-C5H5) and (.mu.-H)2Ru3(.mu.3-CPh)(.mu.-CO)(CO)6(.eta.5-C5H5). Crystal structures of Ru3(.mu.3-CPh)(.mu.-CO)2(CO)6(.eta.5-C5H5) and Ru3(.mu.3-CPh)(.mu.-CO)3(.eta.5-C5H5)3

✍ Nevinger, Leigh R.; Keister, Jerome B.; Lake, Charles H.; Churchill, Melvyn Rowe 📂 Article 📅 1992 🏛 American Chemical Society 🌐 English ⚖ 777 KB

Alkyne-induced carbyne-carbyne coupling

Alkyne-induced carbyne-carbyne coupling in the trinuclear bis(carbyne) iron cluster Fe3(CO)9(.mu.3-COC2H5)(.mu.3-CCH3). X-ray structures of Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(OC2H5)C(CH3)C(C6H5)C(C6H5)] and Fe3(CO)6(.mu.-CO)2.mu.3-.eta.4[C(CH3)C(OC2H5)C(Si(CH3)3)C(Si(CH3)3)]

✍ Nuel, Didier; Dahan, Francoise; Mathieu, Rene 📂 Article 📅 1985 🏛 American Chemical Society 🌐 English ⚖ 880 KB

Addition of small molecules to (.eta.-C5

Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 6. Formation of the .mu.-alkylidene complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CHR)(.mu.-CF3C2CF3) (R = CO2Et, SiMe3, CF3, or CH:CH4) and coupling reactions of the alkyne and carbene ligands within these complexes. X-ray crystal structure of (.eta.-C5H5)2Rh2(CO){C(CF3)C(CF3)CH(CO2Et)}

✍ Dickson, Ron S.; Fallon, Gary D.; Jenkins, Susan M.; Nesbit, Rhonda J. 📂 Article 📅 1987 🏛 American Chemical Society 🌐 English ⚖ 944 KB

Thermodynamic and kinetic aspects of sub

Thermodynamic and kinetic aspects of substituent effects on the redox properties of the carbonyl-bridged dirhodium complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-t-BuC2-t-Bu) and (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CF3C2CF3)

✍ Bixler, J. W.; Bond, A. M.; Dickson, R. S. 📂 Article 📅 1986 🏛 American Chemical Society 🌐 English ⚖ 914 KB

Alkylidyne-alkylidyne coupling induced b

Alkylidyne-alkylidyne coupling induced by carbon monoxide addition to the bis(alkylidyne) cluster Fe3(CO)9(.mu.3-CCH3)(.mu.3-COC2H5): an unexpected reversible reaction. X-ray structure of Fe3(CO)9[P(C6H5)3](.mu.3-.eta.2-CH3C.tplbond.COC2H5)

✍ Nuel, Didier.; Dahan, Francoise.; Mathieu, Rene. 📂 Article 📅 1985 🏛 American Chemical Society 🌐 English ⚖ 541 KB

Reactions between transition-metal alkyn

Reactions between transition-metal alkynyl complexes and nucleophiles: syntheses and crystal structures of [Fe2(CO)(.mu.-CO){.mu.-.eta.3(.sigma.)-C(O)C2(CH3)[C(O)R]}(.eta.5-C5H5)(.eta.5-C5(R')5)] (R = CH3, C6H5, n-C4H9; R' = H, CH3)

✍ Wong, Andrew.; Pawlick, Robert V.; Thomas, Christopher G.; Leon, David R.; Liu, 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 346 KB