Cation/anion dependence of metal ammine borohydrides/chlorides studied by ab initio calculations
β Scribed by Yamane, Aki; Shimojo, Fuyuki; Ichikawa, Takayuki; Kojima, Yoshitsugu
- Book ID
- 122721141
- Publisher
- Elsevier
- Year
- 2014
- Tongue
- English
- Weight
- 365 KB
- Volume
- 1039
- Category
- Article
- ISSN
- 2210-271X
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## Abstract Copper chloride anion clusters with both copper oxidation states can be made by laser desorption of CuCl~2~ crystals. We have used this method to study the dissociation characteristics of such cluster ions. The stability and the structure of the observed complexes were probed by __ab in
A recently developed ab initio MO theory including solvent effects has been applied to a typical cation-anion reaction, the SN2 reaction of the trimethylsulfonium cation with the chloride anion. In the gas phase, the trimethylsulfonium and chloride ions are unstabilized, and the reaction is expected