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Cation valencies in cubic and tetragonal Mn1.9Fe1.1O4

โœ Scribed by M.K. Hucl; F. Van der Woude; G.A. Sawatzky


Publisher
Elsevier Science
Year
1972
Tongue
English
Weight
162 KB
Volume
42
Category
Article
ISSN
0375-9601

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Calcium Insertion in the Na4Mn9O18 Tunne
โœ N. Floros; C. Michel; M. Hervieu; B. Raveau ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 541 KB

A new mixed valent manganese oxide, Na 1.1 Ca 1.8 Mn 9 O 18 , with a tunnel structure closely related to that of Na 4 Mn 9 O 18 has been synthesized. It crystallizes in the Pnma space group with a โ€ซุโ€ฌ 26.418(2) A s , b โ€ซุโ€ฌ 5.6468(4) A s , and c โ€ซุโ€ฌ 9.1384(8) A s . Its structural study, combining X-r