Cation exchange in the desorption of crown ether complexes in strong electric field gradients
β Scribed by Neil B.H. Henis; Tim L. Youngless; Maurice M. Bursey
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 199 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0020-1650
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π SIMILAR VOLUMES
The generalised polarisabilities describing the response to an applied field of the electric field gradients at the nuclei of BrCl are calculated ab initio using the correlated CCSD(T) method with relativistic corrections estimated by the Douglas-Kroll 'no-pair' model. The magnitudes of 86.9 and 42.
The complexation of a series of bis(benzo crown ether)s of variable ring size and length of the linking chain with Na , K and Cs was studied in the gas phase by fast atom bombardment mass spectrometry in nitrobenzyl alcohol/glycerol as a matrix. Both 2:1 (conventionally within the cavity of the crow