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Cation effects in nanocrystalline solar cells

✍ Scribed by David F. Watson; Gerald J. Meyer


Publisher
Elsevier Science
Year
2004
Tongue
English
Weight
359 KB
Volume
248
Category
Article
ISSN
0010-8545

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✦ Synopsis


Over the past 20 years, the pioneering work of Michael GrΓ€tzel and coworkers has led to the development of highly efficient nanocrystalline dye-sensitized solar cells. The energy conversion mechanism of dye-sensitized solar cells involves photoinduced interfacial electron transfer reactions. The cation concentration at the semiconductor/electrolyte interface exerts a profound influence on the mechanism and efficiency of these electron transfer reactions. In this article, we review significant contributions to the understanding of cation effects in nanocrystalline solar cells.


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2AY (UK) [\*\*] The authors thank FAPESP (Proc. Nr. 98/10567-6 and Nr. 96/09983-6) and EPSRC for financial support, and Daiso Co. Ltd. Osaka, Japan for providing Epichlomer samples. We also acknowledge Richard Wills and Thierry Lutz for the fabrication of the TiO 2 particles employed in this study;