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Cation disorder in Bi2Ln2Ti3O12 Aurivillius phases (Ln = La, Pr, Nd and Sm)

✍ Scribed by Neil C Hyatt; Joseph A Hriljac; Tim P Comyn

Book ID
114066328
Publisher
Elsevier Science
Year
2003
Tongue
English
Weight
201 KB
Volume
38
Category
Article
ISSN
0025-5408

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Preparation, Crystal Structures, and Pro
Preparation, Crystal Structures, and Properties of Rhenates with Multiple Re–Re Bonds: Ln2ReO5 (Ln=Sm, Eu, Gd), Ln3Re2O9 (Ln=Pr, Nd, Sm), and Ln4Re6O19 (Ln=La–Nd)
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Most of the title compounds were prepared by reaction of the rare-earth metaperrhenates Ln(ReO 4 ) 3 with the rare-earth metals in sealed silica tubes. Nd 4 Re 6 O 19 was obtained by reaction of the intermetallic compound NdRe 2 with the metaperrhenate Nd(ReO 4 ) 3 . The compounds Ln 2 ReO 5 crystal