Synthesis and Cation Binding Properties of Triester Calix[4]arenes and Calix[4]quinones. -The triester methyl calix[4]arene shows the highest extraction of sodium ion. -(NAM, K.
Cation Binding Selectivity of Partially Substituted Calix[4]arene Esters
✍ Scribed by Aogán Lynch; Kathrin Eckhard; Gillian McMahon; Rachel Wall; Paddy Kane; Kieran Nolan; Wolfgang Schuhmann; Dermot Diamond
- Publisher
- John Wiley and Sons
- Year
- 2002
- Tongue
- English
- Weight
- 189 KB
- Volume
- 14
- Category
- Article
- ISSN
- 1040-0397
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## Abstract A general method has been developed for the preparation of bis(syn‐proximally) functionalized calix[4]arenes (6, 8–10). Starting from __p‐tert__‐butylcalix[4]arene 1a and calix[4]arene 1b syn‐proximally __dialkylated__ calix[4]arenes 2a and 2b, 4, and 5, respectively, were obtained by t
## Abstract The complex stability constants (__K__~S~) and thermodynamic parameters (Δ__G__°, Δ__H__°, and __T__Δ__S__°) for 1:1 intermolecular complexation of water‐soluble calix[4]arene tetrasulfonate (**CAS**) and thiacalix[4]arene tetrasulfonate (**TCAS**) with pyridinium guest ions **1–10** ha