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Cation arrangement in a few oxides with crystal structures of the spinel type

✍ Scribed by E. J. W. Verwey; J. H. de Boer


Publisher
Elsevier Science
Year
2010
Tongue
English
Weight
578 KB
Volume
55
Category
Article
ISSN
0165-0513

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The structure of Zn-Co spinel prepared by coprecipitation was studied by IR spectroscopy. The characteristic bands of extra OH y and H O q groups were shown to exist in IR spectra up to 7008C. Comparing IR spectra of a poorly crystallized 3 low temperature catalyst with that of a perfect Zn-Co spine

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We report on the synthesis and structure of InSnCl 3 and InSnBr 3 . Their structure represents a new ABX 3 structure type which will only be found for compounds with large cations A and B having an ns 2 electron con5guration. The cations have high coordination numbers and therefore their coordinatio