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Cathodic reduction of cinnamoyl chloride

✍ Scribed by A. Guirado; F. Barba; J. Martin

Publisher: Elsevier Science
Year: 1984
Tongue: English
Weight: 167 KB
Volume: 29
Category: Article
ISSN: 0013-4686
DOI: 10.1016/0013-4686(84)87114-5

No coin nor oath required. For personal study only.

✦ Synopsis

The electrolysis ofcinnamoyl chloride in dry acetoneanhydrous lithiumperchlorate is carried out under controlled cathodic potential on a preparative scale. The ketonic reaction products are identified and their formation is rationalized through the eleetroneneration ofcinnamoyl free radical, hydrogen abstraction and dimerization of the aldoketene~ntermediate.

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