Cathodic Cleavage of some cyclic sulphones
โ Scribed by Bo Lamm
- Book ID
- 108383392
- Publisher
- Elsevier Science
- Year
- 1972
- Tongue
- French
- Weight
- 94 KB
- Volume
- 13
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
Airstract -Allylic and benzylicsulphones were reduced in aprotic solvents on a stationary mercury electrode. For slow sweep rates, it was shown that electrogenerated bases were able to deprotonate the substrate and consequently to form inactive anions. A comparison between the electrochemical behavi
The generation of sulphene intermediates has attracted considerable attention over the last few years.' Such intermediates have been suggested in the thermolytic\* and photolytic3\*4 fragmentation of cyclic sulphones. Trapping experiments indicate3 that vinyl sulphenes (2') are involved in the photo
Reaction of ffketo sulphones with 2N NaOH, at 70 \*C, in aqueous media and in presence of cetyttrimethylammonium chloride (CTACI), produces the C-C bond fission between the carbonyl group and the carbon bearing the sulphone.