✦ LIBER ✦

Cathodic cleavage of carbon - oxygen bonds of ethers. A selective monosubstitution of triphenylene hexaethers in electrophilic media

✍ Scribed by Ahmed Ghanimi; Jacques Simonet

Publisher: Elsevier Science
Year: 1993
Tongue: French
Weight: 190 KB
Volume: 34
Category: Article
ISSN: 0040-4039
DOI: 10.1016/s0040-4039(00)91823-9

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✦ Synopsis

The sektivr cleavage limttcd to one corbon -oxygen bond for haadoq~iphayhm can be cathodkdly pu&nnai tit qwottc dtpokw lolwnts. Thejtltctioen

📜 SIMILAR VOLUMES

Cathodic cleavage of carbonoxygen bond—

Cathodic cleavage of carbonoxygen bond—II electroreduction of ethers in weakly acidic organic solvents

✍ E. Santiago; J. Simonet 📂 Article 📅 1975 🏛 Elsevier Science 🌐 English ⚖ 303 KB

Electrochemical reduction of ethers has been studied both in aprotic and in protic solvents. The cleavage of the carbon-oxygen bond mainly occurs for benzylic and allylic ethers but it can lx observed a partial reduction of the electrophore leading to a saturated ether. Vinylic and allenic ethers ar