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catena-(μ3-Bromo)di(μ2-bromo)bromo(18-crown-6)dilead(II): Synthesis and crystal structure

✍ Scribed by A. N. Chekhlov


Book ID
111458172
Publisher
SP MAIK Nauka/Interperiodica
Year
2008
Tongue
English
Weight
189 KB
Volume
34
Category
Article
ISSN
1070-3284

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✍ Cui, Yun-Cheng ;Che, Guang-Bo ;Lin, Xian-Feng ;Liu, Chun-Bo 📂 Article 📅 2006 🏛 International Union of Crystallography 🌐 English ⚖ 97 KB

The title complex, [Hg~2~Br~4~(C~7~H~16~S~2~)]~n~, has a chain structure. Two bridging Br atoms and two terminal Br atoms coordinate to two Hg^II^ atoms, forming an (HgBr~2~)~2~ dimer, which is located on an inversion center. The 1,3-bis(ethylsulfanyl)propane ligands, which lie on a twofold axis, br