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catena-Poly[[[aqua(pyrazino[2,3-f][1,10]phenanthroline)copper(II)]-μ-benzene-1,3-dicarboxylato] N,N-dimethylacetamide monohydrate]

✍ Scribed by Zhang, Wen-Zhi

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
988 KB
Volume
63
Category
Article
ISSN
1600-5368

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catena-Poly[[[(pyrazino[2,3-f][1,10]phen
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In the title compound, {[Cu(C~14~H~8~O~5~)(C~14~H~8~N~4~)]·H~2~O}~__n__~, the Cu^II^ atom adopts a distorted __cis__-CuN~2~O~2~ square-planar coordination geometry. 4,4′-Oxydibenzoate (__L__) ligands link the Cu^II^ atoms, generating a helical chain. Neighbouring chains are linked through π–π intera

catena-Poly­[[[aqua(1,10-phenanthroline)
catena-Poly­[[[aqua(1,10-phenanthroline)copper(II)]-μ-isophthalato] N,N-di­methyl­form­amide solvate monohydrate]
✍ Xiao, Hong-Ping ;Li, Xin-Hua ;Hu, Mao-Lin 📂 Article 📅 2004 🏛 International Union of Crystallography 🌐 English ⚖ 322 KB

In the title complex, {[Cu(C 8 H 4 O 4 )(C 12 H 8 N 2 )(H 2 O)]Á-C 3 H 7 NOÁH 2 O} n , the Cu atom is surrounded by two O atoms from two isophthalate dianions, an aqua O atom and two N atoms from a phenanthroline heterocycle in a distorted square-pyramidal geometry. The isophthalate dianion function