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catena-Poly[[aqua(pyrazine-2-carboxylato)cobalt(II)]-μ-pyrazine-2-carboxylato]

✍ Scribed by Gao, Yu-Xiang ;Wang, Li-Bin ;Niu, Yan-Ling ;Hao, Lu-Jiang


Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
753 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis


catena-Poly[[aqua(pyrazine-2-carboxylato)cobalt(II)]--pyrazine-2-carboxylato]


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The title compound, [Mn(C 5 H 3 N 2 O 2 ) 2 (H 2 O)] n , prepared by hydrothermal synthesis, is isostructural with its Fe II , Co II , Ni II and Cu II analogues. The asymmetric unit contains two bidendate pyrazine-2-carboxylate anions coordinated to Mn II in the equatorial plane through one N and on

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Single-crystal X-ray study T = 298 K Mean (C-C) = 0.006 A R factor = 0.034 wR factor = 0.085 Data-to-parameter ratio = 12.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.

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Single-crystal X-ray study T = 298 K Mean '(C±C) = 0.011 A Ê Disorder in main residue R factor = 0.096 wR factor = 0.297 Data-to-parameter ratio = 10.2 For details of how these key indicators were automatically derived from the article, see http://journals.iucr.org/e.