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catena-Poly[[(2,2′-bipyridine-κ2N,N′)manganese(II)]-μ-3,5-dinitro-2-oxidobenzoato-κ4O,O′:O′,O2]

✍ Scribed by Song, Wen-Dong ;Guo, Xian-Xia ;Rong-Fa, Guo

Publisher
International Union of Crystallography
Year
2007
Tongue
English
Weight
154 KB
Volume
63
Category
Article
ISSN
1600-5368

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✦ Synopsis

In the title complex, [Mn(C~7~H~2~N~2~O~7~)(C~10~H~8~N~2~)]~n~, the Mn^II^ atom has a distorted octahedral coordination geometry, defined by two N atoms from the 2,2′-bipyridine ligand and four O atoms from two 3,5-dinitrosalicylate dianions. One carboxylate O atom acts as a bridge between adjacent metal centres to form a one-dimensional chain. The Mn...Mn distance is 4.315 (6) Å. The crystal packing is stabilized by intermolecular C—H...O hydrogen interactions.

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