Chemically Triggered CโON Bond Homolysis
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Elena Bagryanskaya; Paul Brรฉmond; Mariya Edeleva; Sylvain R. A. Marque; Dmitriy
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Article
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2011
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John Wiley and Sons
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English
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## Abstract In recent work, a 15โfold increase in the CโON bond homolysis rate constant __k__~d~ of 4โpyridylethylโSG1โbased alkoxyamine was observed upon protonation of the pyridyl moiety in organic solvent. In this report, the pH dependence of __k__~d~ (p__K__~a~ = 4.7) is investigated in D~2~O/C