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Catalyzed oxidation of alcohols and aldehydes with iodosylbenzene

✍ Scribed by Paul Müller; José Godoy

Book ID
104235205
Publisher
Elsevier Science
Year
1981
Tongue
French
Weight
182 KB
Volume
22
Category
Article
ISSN
0040-4039

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✦ Synopsis

1211 Geneve 4, Suisse swrunury. RuC12(PPh3), catalyzes oxidation of alcohols to carbonyl compounds by iodosylbenzene and that of aldehydes to carboxylic acids.

Catalyzed oxidation of primary alcohols with phenyliodosodiacetate affords aldehydes.

📜 SIMILAR VOLUMES

Ru-Catalyzed Oxidations with Iodosylbenz
Ru-Catalyzed Oxidations with Iodosylbenzene Derivatives. Substituent Effects on Selectivity in Oxidation of Sulfides and Alcohols
✍ Paul Müller; José Godoy 📂 Article 📅 1983 🏛 John Wiley and Sons 🌐 German ⚖ 360 KB

## Abstract Oxidation of sulfides with PhIO/RuCl~2~ (PPh~3~)~3~ leads to sulfones. Electronwithdrawing substituents in the aromatic ring of PhIO reduce the reactivity and improves selectivity of the system. Thus, with __m__‐iodosylbenzoic acid sulfides are converted to sulfoxide. Under the same con