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Catalyzed decomposition of organic hydroperoxides

✍ Scribed by R.A. Sheldon; J.D. Chen; J. Dakka


Book ID
107894711
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
110 KB
Volume
15
Category
Article
ISSN
0144-2449

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The decomposition of organic hydroperoxi
✍ A. W. de Ruyter van Steveninck; E. C. Kooyman πŸ“‚ Article πŸ“… 2010 πŸ› Elsevier Science 🌐 English βš– 799 KB

## Abstract The HClO~4~‐catalyzed decomposition of a number of alkylbenzyl hydroperoxides has been investigated by a study of the reaction kinetics in 50% w ethanol at 50Β°C. A Hammett relation (__p__ = ‐4.57) has been found to exist for the decomposition of ring‐substituted Ξ±,α‐dimethylbenzyl hydro