𝔖 Bobbio Scriptorium
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Catalytic, Stereoselective Glycosylation—Spiroketalization of 3,4,5-Tri-O-benzyl-β-D-fructopyranose Generating Di-D-fructopyranose-1,2′-2,1′-dianhydride.

✍ Scribed by Eisuke Kaji; Reiko Saiga; Emiko Kurimoto; Takashi Nishino


Publisher
John Wiley and Sons
Year
2007
Weight
21 KB
Volume
38
Category
Article
ISSN
0931-7597

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The molecule is a derivative of the naturally occurring carbohydrate D-fNCtOSe. The data reported here indicate that the ketose six-membered ring is constrained by the presence of two fused five-membered rings into the 3So conformation. These findings agree with the n.m.r.-spectroscopic results for