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Catalytic Roles of Metal Centers in the Selective Oxidation of Cyclohexanol by Cr(salten) Complexes Immobilized on MCM-41

✍ Scribed by Xiaoli Wang, Gongde Wu, Yunbo Xue, Fang Zhang, Xianfeng Liu, Keqiang Ding

Book ID
118797514
Publisher
Springer US
Year
2012
Tongue
English
Weight
310 KB
Volume
143
Category
Article
ISSN
1011-372X

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The chiral salen Mn(III) complexes were heterogenized on the siliceous MCM-41 by a new grafting method using (3-aminopropyl) trimethoxysilane and 2,6-diformyl-4-tert-butylphenol. The immobilized chiral salen Mn(III) complexes were stable during the reaction and exhibited a relatively high enantiosel