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Catalytic reduction ofα-alkylfurfuryl alcohols to alkylfurans

✍ Scribed by N. I. Shuikin; I. F. Bel'skii


Book ID
112490681
Publisher
Springer
Year
1958
Tongue
English
Weight
83 KB
Volume
7
Category
Article
ISSN
1573-9171

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A new system for catalytic enantioselect
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The reduction of a variety of achiral ketones with catecholborane as stoichiometric reductant and 0.1 equiv of oxaxaborolidine 2 as catalyst in toluene at -78'C proceeds in > 95% yield and with enantioselectivities in the range 30: 1 to 9: 1, depending on substrate. This reduction procedure is espec