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Catalytic Reactions in Direct Ethanol Fuel Cells

โœ Scribed by Dr. In Kim; Dr. Oc Hee Han; Dr. Seen Ae Chae; Dr. Younkee Paik; Sung-Hyea Kwon; Dr. Kug-Seung Lee; Dr. Yung-Eun Sung; Dr. Hasuck Kim


Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
603 KB
Volume
123
Category
Article
ISSN
0044-8249

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Thermodynamic and kinetic considerations for the ethanol electrooxidation in a proton exchange membrane fuel cell (PEMFC) were discussed. Theoretical calculations show that direct ethanol fuel cells (DEFCs) exhibit better exergic efficiency than ethanol reforming PEMFC. The thermodynamic analysis sh

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โœ S.Y. Shen; T.S. Zhao; J.B. Xu ๐Ÿ“‚ Article ๐Ÿ“… 2010 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 996 KB

Owing to the formation of an oxametallacyclic conformation, the CeC bond cleavage is the preferential channel for the ethanol dissociation on the Rh surface, the addition of Rh to Pt can increase the CO 2 yield during the ethanol oxidation. However, in acidic media the slow oxidation kinetics of CO