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Catalytic properties of rhodium hydridocarbonyl trithienyl-phosphine complexes in the homogeneous hydrogenation and isomerization of unsaturated compounds

✍ Scribed by A. A. Dudinov; Ya. L. Gol'dfarb; E. F. Litvin; L. M. Kozlova; B. S. Bogdanov


Book ID
112377192
Publisher
Springer US
Year
1986
Tongue
English
Weight
383 KB
Volume
22
Category
Article
ISSN
0009-3122

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## Abstract Mixed N‐heterocyclic carbene‐substituted phosphine and phosphite complexes of rhodium were prepared, starting from [Rh(COE)~2~Cl]~2~ (COE=cyclooctene) by addition of free N‐heterocyclic carbenes (NHC) and PR~3~. All new complexes were characterized by spectroscopy. In addition, the stru