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Catalytic performance and characterization of RhVO4/SiO2 for hydroformylation and CO hydrogenation

✍ Scribed by Takashi Yamagishi; Ippei Furikado; Shin-ichi Ito; Toshihiro Miyao; Shuichi Naito; Keiichi Tomishige; Kimio Kunimori

Publisher
Elsevier Science
Year
2006
Tongue
English
Weight
689 KB
Volume
244
Category
Article
ISSN
1381-1169

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The influence of the cationic promoters (M = Li, Na, K, Rb, Cs) on silica-supported rhodium catalysts was examined in the hydroformylation of propene at 413 K and atmospheric pressure. The catalysts were prepared by aqueous co-impregnation of RhCl 3 β€’3H 2 O and alkali-metal chloride. The rhodium to

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## Abstract Colloids embedded in a silica sol–gel matrix were prepared by using fully alloyed Pd–Au colloids, and pure Pd and Au colloids stabilized with tetraalkylammonium bromide following a modified sol–gel procedure with tetrahydrofuran (THF) as the solvent. Tetraethoxysilicate (TEOS) was used