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Catalytic oxidation of reduced sulfur compounds by homogeneous and heterogeneous Co(II) phthalocyanine complexes

✍ Scribed by Michael R. Hoffmann; Andrew P.K. Hong


Book ID
118035848
Publisher
Elsevier Science
Year
1987
Tongue
English
Weight
831 KB
Volume
64
Category
Article
ISSN
0048-9697

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The Co(H)-catalysed oxidation of alkyl-and aryI-sulfides was achieved under homogeneous and heterogeneous conditions using oxygen or air as the oxidant in the presence of excess aldehyde. The reactions in the homogeneous phase were carried out using the soiuble Co(acac), or WAAEMA), complexes IAAEMA

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Aromatic a-hydroxyketones were easily oxidized by dioxygen in the presence of excess aldehyde or aldoacetal with catalytic amount of Co(II) or Fe(II1) complexes, under homogeneous and heterogeneous conditions. Co(acac), or Fe(acac), were the catalysts used in homogeneous phase reactions whereas Co(I