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Catalytic oxidation of olefins and alcohols with hydrogen peroxide in a two-phase system giving mono- and dicarboxylic acids

✍ Scribed by Z. P. Pai; A. G. Tolstikov; P. V. Berdnikova; G. N. Kustova; T. B. Khlebnikova; N. V. Selivanova; A. B. Shangina; V. G. Kostrovskii


Publisher
Springer
Year
2005
Tongue
English
Weight
359 KB
Volume
54
Category
Article
ISSN
1573-9171

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Mntrimethyltriazacyclononane/ascorbic a
✍ Albrecht Berkessel; Christoph A. Sklorz 📂 Article 📅 1999 🏛 Elsevier Science 🌐 French ⚖ 253 KB

The system comprised of manganese(II) acetate or sulfate, 1,4,7-trimethyl-1,4,7-triazacyclononane (TMTACN) and ascorbic acid efficiently catalyzes the epoxidation of olefins and the oxidation of alcohols with hydrogen peroxide. For example, in the presence of as little as 0.03 mol% of Mn 2÷, methyl