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Catalytic oxidation of mono-ethenoid fatty acids; The catalytic influence of cations of metals of the typical and transitional series in autoxidation processes

✍ Scribed by Skellon, J. H.

Publisher
Wiley (John Wiley & Sons)
Year
1950
Weight
459 KB
Volume
69
Category
Article
ISSN
0368-4075

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✦ Synopsis

Abstract

The influence of metal cations of the typical and transitional series in catalytic oxidation of oleic acid has been investigated over a wide range of conditions. The results of a series of oxidations, in which the catalyst metal ion content was adjusted to a constant value, have afforded new information concerning the intrinsic effect of metal ions on oxygen absorption by mono‐ethenoid acids.

A new relative order of efficiency of metal cation catalysts in autoxidation processes has been obtained. The catalytic activity of the metal ions is correlated with their atomic structure and is shown to be a periodic function. A theory of catalytic activity is advanced applicable to metals used for promoting gaseous oxidation of unsaturated fatty acids and esters, and for the oxidation of parent oils.

πŸ“œ SIMILAR VOLUMES

Some metallic compounds of unsaturated f
Some metallic compounds of unsaturated fatty acids: Their preparation and properties with special reference to the influence of the acidic group in autoxidation processes
✍ Skellon, J. M. ;Spence, J. W. πŸ“‚ Article πŸ“… 1948 πŸ› Wiley (John Wiley & Sons) βš– 518 KB

## Abstract The experimental preparation of certain less common, pure metallic compounds of selected unsaturated fatty acids is described. The metal content of these compounds has been determined, and the probability that certain of these derivatives may be physical complexes, rather than true chem