Catalytic oxidation of cyclohexanone with chloric acid: reaction kinetics
β Scribed by A. Borsari; F. Trifiro; A. Vaccar
- Book ID
- 103691432
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 406 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0304-5102
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π SIMILAR VOLUMES
## Abstract The oxidation of cyclohexanol with nitric acid to adipic acid proceeds via two stable intermediates known from the literature^1^ viz. 6βhydroxyiminoβ6βnitro hexanoic acid and the hemihydrate of 1,2βcyclohexanedione, two substances forming beside each other in a given ratio. This ratio c
## Abstract The stablest intermediate product formed in the oxidation of cyclohexanol and cyclohexanone is 6βhydroxyiminoβ6βnitro hexanoic acid (nitrolic acid). In the temperature range investigated it yields over 90% of adipic acid and N~2~O. In addition, a small amount of a still unidentified byβ