Catalytic oligomerization in the reaction of diphenylacetylene with chromium vapor
β Scribed by Tomi T.-T. Li; Carl H. Brubaker Jr.
- Publisher
- Elsevier Science
- Year
- 1982
- Tongue
- English
- Weight
- 120 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0020-1693
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Reaction of alkynes having bulky substituents with pentacarbonyl[cyclopropyl(methoxy)methylene]chromium(0) (1) provided cyclopentadienone derivatives. Cyclopentadienones were easily hydrogenated to the corresponding cyclopentenones using chromium hexacarbonyl and water, with no problems resutting fr
## Abstract __The effect of a single water molecule on the reaction mechanism of the gasβphase reaction between formic acid and the hydroxyl radical was investigated with highβlevel quantum mechanical calculations using DFTβB3LYP, MP2 and CCSD(T) theoretical approaches in concert with the 6β311+G(2