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Catalytic Influence of Certain Foreign Gases on the Thermal Decomposition of Di-Tertiary Butyl Peroxide

โœ Scribed by Bose, A. N.; Hinshelwood, C.


Book ID
120144995
Publisher
The Royal Society
Year
1959
Tongue
English
Weight
477 KB
Volume
249
Category
Article
ISSN
0962-8444

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The thermal decomposition of di-tertiary-butyl peroxide vapor is exothermic, and, in a closed vessel, the resultant self-heating may lead to ignition. The parameters that determine the criteria for ignition are encapsulated in Frank-Kamenetskii's 6, and they include exothetrnicity and Arrhenius cons