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Catalytic Hydrosilylation of Acetylenes Mediated by Phosphine Complexes of Cobalt(I), Rhodium(I), and Iridium(I).

โœ Scribed by Leslie D. Field; Antony J. Ward

Book ID
111699546
Publisher
John Wiley and Sons
Year
2004
Weight
208 KB
Volume
35
Category
Article
ISSN
0931-7597

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โœ Dr. J. Peone Jr; Prof. Dr. L. Vaska ๐Ÿ“‚ Article ๐Ÿ“… 1971 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 233 KB

Si-Fluorinated, C-chlorinated carbosilanes such as ( 3 d ) , ( 4 c ] , and ( 5 d ) are readily accessible in good yields, however, by photochlorination of the CH, groups in compounds of type (3 b ) -( 5 b) (see Table ). 'H-NMR studies of the reaction course in CC1, solution show that partially chlor