Rhodium(III) and Iridium(III) Complexes
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Gerald Kohl; Hans Pritzkow; Markus Enders
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Article
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2008
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John Wiley and Sons
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English
⚖ 203 KB
## Abstract Bis(ethene) complexes of rhodium(I) and iridium(I) with 8‐quinolylcyclopentadienyl ligands (Cp^Q^ and Cp^Q^\*) were oxidized by a photochemically induced reaction with chlorine‐containing solvents or by treatment with iodine. Upon this oxidation, the quinoline ring rotates and the N don