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Catalytic Hydrogenation with Rhodium Complexes Containing dipamp-pyrphos Hybrid Ligands

✍ Scribed by Prof. Dr. Ulrich Nagel; Thomas Krink


Publisher
John Wiley and Sons
Year
1993
Tongue
English
Weight
348 KB
Volume
32
Category
Article
ISSN
0044-8249

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Rhodium(III) and Iridium(III) Complexes
✍ Gerald Kohl; Hans Pritzkow; Markus Enders 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 English ⚖ 203 KB

## Abstract Bis(ethene) complexes of rhodium(I) and iridium(I) with 8‐quinolylcyclopentadienyl ligands (Cp^Q^ and Cp^Q^\*) were oxidized by a photochemically induced reaction with chlorine‐containing solvents or by treatment with iodine. Upon this oxidation, the quinoline ring rotates and the N don