Catalytic Hydrogenation of α,β-Unsaturated Ketones. II. The Mechanism of Hydrogenation in Acidic Medium. 1,2
✍ Scribed by AUGUSTINE, ROBERT L.; BROOM, ARTHUR D.
- Book ID
- 127204967
- Publisher
- American Chemical Society
- Year
- 1960
- Tongue
- English
- Weight
- 354 KB
- Volume
- 25
- Category
- Article
- ISSN
- 0022-3263
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📜 SIMILAR VOLUMES
In the asymmetric synthesis of chiral compounds, the reduction of prochiral unsaturated reactants has a great importance. (S)-proline as a chiral auxiliary is used in the hydrogenations of exocyclic ␣,-unsaturated ketones with palladium on carbon catalysts, producing the corresponding saturated ke
Chiral ruthenium hydrides : HRuCl(TRPC)2 and H2Ru(TBPC)2 catalyse the hydrogenation of a-&unsaturated ketones to ketones (e.e. 62 X). Asymmetric hydrogenation of prochiral olefins in the presence of chiral rhodium catalyst 1 is now a useful preparative tool for many a-aminoacids