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Catalytic Hydrogenation in Supercritical CO 2 : Kinetic Measurements in a Gradientless Internal-Recycle Reactor

โœ Scribed by Bertucco, Alberto; Canu, Paolo; Devetta, Luca; Zwahlen, Andreas G.

Book ID
121089329
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
187 KB
Volume
36
Category
Article
ISSN
0888-5885

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The advantage of coupling a diffuse-reflectance infrared cell with a continuous-feed recycle reactor for in situ kinetic and mechanistic studies is illustrated in the study of CO, methanation over Ru/TiO,. From transient and steady-state experiments, metal-adsorbed CO is identified as a major reacti