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Catalytic Hydrogenation by Triruthenium Clusters: A Mechanistic Study with Parahydrogen-Induced Polarization

✍ Scribed by Damir Blazina; Simon B. Duckett; Paul J. Dyson; Joost A. B. Lohman


Publisher
John Wiley and Sons
Year
2003
Tongue
English
Weight
406 KB
Volume
9
Category
Article
ISSN
0947-6539

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A Parahydrogen Study of Catalytic Hydrog
✍ Tom G. Prestwich; Damir Blazina; Simon B. Duckett; Paul J. Dyson 📂 Article 📅 2004 🏛 John Wiley and Sons 🌐 English ⚖ 141 KB 👁 1 views

## Abstract The diphosphane‐substituted clusters [Ru~3~(CO)~10~(dppe)] and [Ru~3~(CO)~8~(dppe)~2~] [dppe = 1,2‐bis(diphenylphosphanyl)ethane] are shown to catalytically hydrogenate diphenylacetylene. This process is highly solvent‐dependent with fragmentation dominating in low‐polarity solvents, wh