A Parahydrogen Study of Catalytic Hydrog
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Tom G. Prestwich; Damir Blazina; Simon B. Duckett; Paul J. Dyson
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Article
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2004
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John Wiley and Sons
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English
⚖ 141 KB
👁 1 views
## Abstract The diphosphane‐substituted clusters [Ru~3~(CO)~10~(dppe)] and [Ru~3~(CO)~8~(dppe)~2~] [dppe = 1,2‐bis(diphenylphosphanyl)ethane] are shown to catalytically hydrogenate diphenylacetylene. This process is highly solvent‐dependent with fragmentation dominating in low‐polarity solvents, wh