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Catalytic hydroalkoxycarbonylation of olefins in the presence of the Pd(PPh3)4-p-TsOH system

โœ Scribed by Kh. A. Suerbaev; K. M. Shalmagambetov


Publisher
Springer
Year
2004
Tongue
English
Weight
21 KB
Volume
74
Category
Article
ISSN
1070-3632

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The hydroesterification of cyclohexene is catalyzed by a preformed Pd(PPh 3 ) 2 (TsO) 2 complex I in methanol as solvent. The effect of PPh 3 , TsOH, and water on the TOF has been evaluated. The system I/PPh 3 /TsOH = 1/6/8, in the presence of 800 ppm of H 2 O, at 373 K and under 2.0 MPa of CO leads