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Catalytic Generation of Cesium Acetylide by CsF: Synthesis of 1,3-Benzothiazines from Cyclic Sulfenamides

✍ Scribed by Spitz, Cédric; Lohier, Jean-François; Reboul, Vincent; Metzner, Patrick


Book ID
120592800
Publisher
American Chemical Society
Year
2009
Tongue
English
Weight
767 KB
Volume
11
Category
Article
ISSN
1523-7060

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Asymmetric Synthesis of Functionalized Secondary Alcohols by Catalytic Ring-Cleavage Reactions of Cyclic Acetals Derived from (R)-1,3-Butanediol. -Optically active B-phenyloxazaborolidinones derived from sulfonamides of α-amino acids are shown to be efficient catalysts for the cleavage of cyclic ac