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Catalytic evaluation of perovskite-type oxide LaNi1−xRuxO3 in methane dry reforming

✍ Scribed by Genira Carneiro de Araujo; Sania Maria de Lima; José Mansur Assaf; Miguel Antonio Peña; José Luís García Fierro; Maria do Carmo Rangel


Publisher
Elsevier Science
Year
2008
Tongue
English
Weight
903 KB
Volume
133-135
Category
Article
ISSN
0920-5861

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✦ Synopsis


The methane reforming with carbon dioxide (dry reforming) has been proposed as one of the most promising technologies for producing hydrogen by the use of two greenhouse gases. However, undesirable coke formation is the crucial issue to develop efficient catalysts for the reaction. In order to find alternative catalysts, which can be more resistant against coke deactivation, perovskite-type oxides LaRu x Ni 1Àx O 3 (0.0 < x < 1.0) were studied in this work. Samples were prepared by thermal decomposition of amorphous citrate precursors followed by heating at 800 or 1000 8C, for 12 h, in air. The solids were characterized by X-ray diffraction, temperature-programmed reduction, temperatureprogrammed desorption, specific surface area measurements and X-ray photoelectron spectroscopy. The catalysts were reduced under hydrogen and tested in methane dry reforming at 1 atm and 750 8C. The coke produced was characterized by thermogravimetry, carbon measurement and scanning and transmission electron microscopy. The oxide precursors showed low specific surface areas and different reducing behavior. All catalysts were active in the reaction. They all produced filamentous coke but it was not harmful to the catalysts. Nickel is more active and selective to hydrogen than ruthenium but the later improved the stability of the catalysts decreasing coke formation. The most promising catalyst was the LaNi 0.8 Ru 0.2 O 3 sample, which was the most resistant against coke deposition.


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Perovskite-Type Oxides: II. Redox Proper
✍ Luciana Lisi; Giovanni Bagnasco; Paolo Ciambelli; Sergio De Rossi; Piero Porta; 📂 Article 📅 1999 🏛 Elsevier Science 🌐 English ⚖ 178 KB

Redox properties of high-surface-area LaM 1؊x Cu x O 3 (M ‫؍‬ Mn or Co) perovskites prepared by the citrate method were studied by H 2 TPR and O 2 TPD techniques. We have found that the reduction of Mn 4؉ occurs in all La+Mn+Cu perovskites at temperatures lower than that of Co 3؉ in La+Co+Cu samples