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Catalytic ethylene polymerization by the titanium-polyhedral oligomeric silsesquioxane-Et3Al2Cl3system

โœ Scribed by Akshay M. Mehta; Gopal L. Tembe; Parimal A. Parikh; Girish N. Mehta


Book ID
106513297
Publisher
Springer-Verlag
Year
2011
Tongue
English
Weight
273 KB
Volume
104
Category
Article
ISSN
1878-5190

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Studies of Ziegler-type catalysts for th
โœ E.W. Duck; D. Grant; J.R. Horder; D.K. Jenkins; A.E. Marlow; S.R. Wallis; A.G. D ๐Ÿ“‚ Article ๐Ÿ“… 1974 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 626 KB

VOCla-Et3A12Cl 3 (chlorinated activator) catalysts have been employed for the polymerization of ethylene at T between 15 and 85 ยฐ in n-hexane. Using butylperchlorocrotonate as the activator, the following catalyst efficiencies (g polymer/gV, hr, atmosphere ethylene in the cap gas) were achieved: l06