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Catalytic Enantioselective Peroxidation of α,β-Unsaturated Ketones

✍ Scribed by Lu, Xiaojie; Liu, Yan; Sun, Bingfeng; Cindric, Brittany; Deng, Li


Book ID
115468500
Publisher
American Chemical Society
Year
2008
Tongue
English
Weight
106 KB
Volume
130
Category
Article
ISSN
0002-7863

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Catalytic enantioselective conjugate add
✍ Marco Bandini; Matteo Fagioli; Paolo Melchiorre; Alfonso Melloni; Achille Umani- 📂 Article 📅 2003 🏛 Elsevier Science 🌐 French ⚖ 174 KB

Chiral [Al(salen) Cl] complex (10 mol%) in the presence of 2,6-lutidine (10 mol%) was found to be effective in catalysing the enantioselective Friedel-Crafts-type conjugate addition of indoles (3) to (E)-arylcrotyl ketones (2), furnishing the corresponding b-indolyl ketones in excellent yield and h