Catalytic Enantioselective Hydrosilylation of Ketones with Rhodium-Phosphite Complexes Containing a TADDOLate and a Dihydrooxazole Unit
✍ Scribed by Dieter K. Heldmann; Dieter Seebach
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- German
- Weight
- 190 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0018-019X
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## Abstract Double‐activation catalysis promises high catalytic efficiency in the enantioselective cyanosilylation of ketones through the combined use of a Lewis acid and a Lewis base. Catalyst systems composed of a chiral salen–Al complex and an N‐oxide have high catalytic turnovers (200 for aroma