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Catalytic Enantioselective Hetero-Diels−Alder Reactions of an Azo Compound

✍ Scribed by Kawasaki, Masanori; Yamamoto, Hisashi

Book ID
120070249
Publisher
American Chemical Society
Year
2006
Tongue
English
Weight
37 KB
Volume
128
Category
Article
ISSN
0002-7863

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Catalytic Enantioselective Hetero-Diels—
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✍ Masanori Kawasaki; Hisashi Yamamoto 📂 Article 📅 2007 🏛 John Wiley and Sons ⚖ 25 KB 👁 1 views

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The first example of a catalytic asymmetric thia hetero-Diels-Alder reaction, in which a chiral Lewis acid activates the thiocarbonyl dienophile, is described. The reactions catalyzed by copper(II)-bis(oxazolines) complexes of three dithioesters with simple dienes (such as cyclopentadiene or 2,3-dim