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Catalytic enantioselective allylic oxidation

✍ Scribed by Minze T. Rispens; Charon Zondervan; Ben L. Feringa


Book ID
108036247
Publisher
Elsevier Science
Year
1995
Tongue
English
Weight
218 KB
Volume
6
Category
Article
ISSN
0957-4166

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πŸ“œ SIMILAR VOLUMES


Catalytic enantioselective allylic oxida
✍ Merritt B. Andrus; Xi Chen πŸ“‚ Article πŸ“… 1997 πŸ› Elsevier Science 🌐 French βš– 481 KB

Asymmetric allylic oxidation of cyclic olefins using a catalytic amount of copper(I) bisoxazoline complexes and new peresters was investigated to give allylic benzoate esters in high selectivity (~80%ee), yield (70-80%), and at reasonable rates (5-7 d) at -20 Β°C in acetonitrile. Cyclohexene reacted