## Abstract For Abstract see ChemInform Abstract in Full Text.
Catalytic Enantioselective Addition of Diethylzinc to Aldehydes Using Aziridine Based Chiral Ligands.
β Scribed by Adnan Bulut; Ayhan Aslan; Enver Cagri Izgue; Oezdemir Dogan
- Publisher
- John Wiley and Sons
- Year
- 2007
- Weight
- 27 KB
- Volume
- 38
- Category
- Article
- ISSN
- 0931-7597
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π SIMILAR VOLUMES
main product 19, ca. 20% of another stereoisomer. This results from a partial racemization of the ketone 5 occurring during its distillation or during the formation of 18. This follows from the condensation of racemic 5 with the aldehyde 15 affording with a 4: 1 selectivity the above mentioned by-pr
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The asymmetric alkylation with diethylzinc of five heterocyclic aldehydes and benzaldehyde (for comparison) has been studied in the presence of two optically active amino alcohols: (S)-2-amino-1-butanol (AB) and (1S,2R)-N,Ndibutylnorephedrine (DBNE). A number of chiral (hetero)aromatic secondary alc