Hydrogenation experiments with batch autoclaves were performed on an Australian Permian bituminous coal (Liddell) using excess of tetralin (3 tetralin: 1 coal by weight) as vehicle. They show that the nickel-molybdenum catalyst, Cyanamid Aero HDS3A, has only a mild effect on the conversion of Liddel
Catalytic effect of mineral matter constituents in a North Assam coal on hydrogenation
β Scribed by Dilip K. Mukherjee; Priya B. Chowdhury
- Publisher
- Elsevier Science
- Year
- 1976
- Tongue
- English
- Weight
- 547 KB
- Volume
- 55
- Category
- Article
- ISSN
- 0016-2361
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β¦ Synopsis
The catalytic effect of the mineral matter constituents as estimated in the ash samples prepared from the various specific gravity fractions of a North Assam coal sample on hydrogenation has been studied. Both iron and titanium present in coal have a catalytic effect on hydrogenation. Pyritic as well as organic sulphur present in the coal appear to be responsible for formation of the catalytically active form of iron sulphide from the iron present in the coal mineral matter. Of the aluminosilicates, kaolinite, which is the major component of coal mineral matter, was found to influence the conversion of coal to gas and benzene-soluble products under the conditions of hydrogenation.
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